What paper types can be loaded in the Multi-Purpose Tray?
The Multi-Purpose Tray supports plain paper, recycled paper, color paper, heavy paper (90 to 163 g/m²), label paper, and envelopes. The cassette does not support label paper, envelopes, or heavy paper above 128 g/m². Auto 2-sided printing is available only for LTR, A4, and LGL paper sizes. (Page 13)
From the official Canon imageCLASS MF416DW Multifunction Printer manual, page 13
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