How do I pair the Samsung Smart Remote to my TV?
When you turn on the TV for the first time, the Samsung Smart Remote pairs to the TV automatically. If it does not pair automatically, point the remote at the remote control sensor of the TV, and then press and hold the Power (⏻) and Return (⏮) buttons simultaneously for 3 seconds or more.
From the official Samsung LS03 Series TV manual, page 16
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