How do I manually pair the Samsung Solarcell Remote to my TV if it doesn't pair automatically?

Point the remote at the front of the TV, then press and hold the TV and Return buttons simultaneously for 3 seconds or more. This manual pairing method should establish the connection between the remote and TV. Note that the Universal Remote function only works normally when using the Samsung Smart Remote that came with the TV. (Page 1)

From the official Samsung SolarCell Remote manual, page 1

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