How do I pair the Samsung Smart Control to my TV for the first time?
Turn on the TV by pointing the Samsung Smart Control at the remote control sensor of the TV, and then pressing the TV button — the TV and Samsung Smart Control pair automatically. The Samsung Smart Control can only connect to one TV at a time, and the remote control sensor's location may vary depending on the model. Note that the Samsung Smart Control is only available with the LED 6400 and 7100 series. (Page 31)
From the official Samsung VRT Smart Care Washing Machine manual, page 31
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