How do I properly fill the RPM 40 pod with e-liquid for the first time?

Fill the pod completely with e-liquid before vaping. After filling a pod with a new coil, let the pod stand for 15 minutes to avoid burning the coil. Then take 2-3 puffs while the power is off and without pressing the Fire Key before you begin vaping normally. (Pages 6, 9)

From the official Smok Rpm 40 manual, page 6

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