How do I add or remove a Z-Wave device from the XL824?
To add a Z-Wave device, navigate to Home Screen > Menu > Smart Home, select Add Device, and follow the device manufacturer's instructions to set the Z-Wave device into learn mode — you will have four minutes to complete this. To remove a device, select Remove Device from the same menu and follow the manufacturer's instructions to set the device into learn mode, also within four minutes.
From the official Trane XL824 Smart Wi-Fi Thermostat manual, page 26
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